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Catalytic reactions of formate: Part 1. Photocatalytic hydrogen production from formate with chromium hexacarbonyl

✍ Scribed by D.E. Linn Jr.; R.B. King; A.D. King Jr.


Publisher
Elsevier Science
Year
1993
Weight
820 KB
Volume
80
Category
Article
ISSN
0304-5102

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## Abstract Anchimerically assisted rearrangement, observed in the fluorination of some α‐amino acids with 70 : 30 (w/w) hydrogen fluoride/pyridine (by weight) in the presence of NaNO~2~, is substantially or fully suppressed by using the less acidic reagent 48 : 52 (w/w) hydrogen fluoride/pyridine.