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Catalytic properties of rhodium organometallic complexes in the reaction of 1-octene oxidation with molecular oxygen

✍ Scribed by Yu. B. Trach; O. I. Makota; T. G. Cherkasova; M. R. Gal’ding; Yu. S. Varshavskii


Book ID
111460601
Publisher
Springer
Year
2010
Tongue
English
Weight
137 KB
Volume
80
Category
Article
ISSN
1070-3632

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Catalytic oxidation of 1-hexene and cycl
✍ P.J Baricelli; V.J Sánchez; A.J Pardey; S.A Moya 📂 Article 📅 2000 🏛 Elsevier Science 🌐 English ⚖ 163 KB

The oxidation of 1-hexene and cyclohexene by molecular oxygen catalyzed by the iridium complexes [Ir(CH 3 CN) 4 NO 2 ](A) 2 (A=PF 6 (1) or BF 4 (2)) has been studied in acetonitrile under P(O 2 )=20 atm, T=120 • C, substrate/catalyst=100, t=20 h. Both complexes are active for oxidizing 1-hexene to 1