Catalytic polycondensation of organosilazanes
β Scribed by A.A. Zhdanov; G.V. Kotrelev; V.V. Kazakova; Yu.L. Tolchinskii
- Book ID
- 118966977
- Publisher
- Elsevier Science
- Year
- 1981
- Weight
- 502 KB
- Volume
- 23
- Category
- Article
- ISSN
- 0032-3950
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Acyclic diene polymerization (ADP) of divinyldimethylsilane in the presence of ruthenium RuCl,(PPh,), and rhodium [RhCl(cod)I2 catalysts led predominantly to linear silylenevinylene oligomers ( M , = 1510 and M J M , = 1.19) if the ruthenium catalyst was used or to mixture of cyclic and linear oligo
Acyclic diene polycondensation (ADP) of diallyldiorganosilanes (CH 2 | CHCH 2 ) 2 SiR 2 (where R Γ Me, Ph), in the presence of various ruthenium and rhodium complexes, led predominantly to linear silylene-propenylene oligomers. Ruthenium catalysts (e.g. RuCl 2 (PPh 3 ) 3 , RuHCl(CO)(PPh 3 ) 3 , and