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Catalytic oxidation of alkanes and alkenes by polymer-anchored amino acid–ruthenium complexes

✍ Scribed by Vaibhav B. Valodkar; Gopal L. Tembe; Marayil Ravindranathan; H.S. Rama

Book ID
108211211
Publisher
Elsevier Science
Year
2004
Tongue
English
Weight
196 KB
Volume
223
Category
Article
ISSN
1381-1169

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Catalytic epoxidation of olefins by poly
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A synthetic strategy was developed to anchor an amino acid L-valine on to styrene-divinylbenzene co-polymer beads with 8% and 6% cross linking. The polymeric ligands containing bidentate N,O donor sites were treated with a solution of ruthenium(III) chloride to form the metal complex on the support.

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## Abstract A (salen)manganese(III) complex bearing a chiral binaphthyl strapping unit catalyzes the enantioselective hydroxylation of indane (up to 34% ee) and the epoxidation of alkenes (up to 93% ee) with iodosylbenzene.