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Catalytic Enantioselective Oxidation of Alkanes and Alkenes Using (Salen)Manganese Complexes Bearing a Chiral Binaphthyl Strapping Unit

✍ Scribed by Shun-Ichi Murahashi; Satoru Noji; Naruyoshi Komiya

Book ID: 101426495
Publisher: John Wiley and Sons
Year: 2004
Tongue: English
Weight: 118 KB
Volume: 346
Category: Article
ISSN: 1615-4150
DOI: 10.1002/adsc.200303190

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✦ Synopsis

Abstract

A (salen)manganese(III) complex bearing a chiral binaphthyl strapping unit catalyzes the enantioselective hydroxylation of indane (up to 34% ee) and the epoxidation of alkenes (up to 93% ee) with iodosylbenzene.

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