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Catalytic oxidation of 1,2-diaminobenzene by the dinuclear cobalt(II)–OBISDIEN dioxygen complex

✍ Scribed by Neiva Deliberali Rosso; Bruno Szpoganicz; Arthur E Martell


Book ID
108331769
Publisher
Elsevier Science
Year
1999
Tongue
English
Weight
160 KB
Volume
287
Category
Article
ISSN
0020-1693

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Dinuclear copper(II) complexes of differing magnetic and redox properties derived from various dinucleating ligands were investigated for their catalytic activity in the oxidation of 3,5-di-t-butylcatechol (3,5-DTBC) and ascorbic acid by oxygen. Poor activity was exhibited by di-#-hydroxocopper(II)