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Catalytic oxidation of aliphatic alcohols in the tetraaquapalladium(ii) complex—iron(iii)—dioxygen system

✍ Scribed by V.V. Potekhin; S.N. Solov"eva; V.M. Potekhin


Book ID
111607548
Publisher
Springer
Year
2003
Tongue
English
Weight
347 KB
Volume
52
Category
Article
ISSN
1573-9171

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Dinuclear copper(II) complexes of differing magnetic and redox properties derived from various dinucleating ligands were investigated for their catalytic activity in the oxidation of 3,5-di-t-butylcatechol (3,5-DTBC) and ascorbic acid by oxygen. Poor activity was exhibited by di-#-hydroxocopper(II)