## Abstract For Abstract see ChemInform Abstract in Full Text.
Catalytic Methods for CH Bond Functionalization: Application in Organic Synthesis
โ Scribed by Fumitoshi Kakiuchi; Naoto Chatani
- Publisher
- John Wiley and Sons
- Year
- 2003
- Tongue
- English
- Weight
- 645 KB
- Volume
- 345
- Category
- Article
- ISSN
- 1615-4150
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โฆ Synopsis
Abstract
The development of catalytic reactions involving carbonโhydrogen bond cleavage is currently one of the most attractive research subjects in organic and organometallic chemistry. About 40 years have past since the pioneering report of the cleavage of C๏ฃฟH bonds with transition metal complexes. Since that time, a vast number of studies of the cleavage of C๏ฃฟH bonds, using stoichiometric amounts of transition metal complexes has appeared. In the last decade, a variety of catalytic reactions involving C๏ฃฟH bond cleavage has been reported. In this review we briefly survey the results of these research activities with respect to the catalytic use of unreactive C๏ฃฟH bonds in organic synthesis.
๐ SIMILAR VOLUMES
Darzens condensation between d-halocarbanions and carbonyl compounds that leads to the formation of glycidic acid derivatives is useful tool in synthesis. Generally the d-halocarbanions are generated by action of dry sodium alkoxides, amide, hydride or other such agents on cc-haloesters, nitriles,
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