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Catalytic isomerization of β-epoxides

✍ Scribed by N. I. Shuikin; M. Bartok; É. Kovach; I. F. Bel'skii

Book ID
112433452
Publisher
Springer
Year
1962
Tongue
English
Weight
189 KB
Volume
11
Category
Article
ISSN
1573-9171

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We report new ruthenium-catalyzed cis-trans isomerization of various functionalized epoxides. Enantiospecific isomerization of chiral epoxides is achieved without loss of enantiopurity, and epimerization occurs only at the epoxide carbon of the activating group.