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A new and efficient catalytic isomerization of cis- and trans-epoxides

✍ Scribed by Ching-Yu Lo; Sitaram Pal; Arjan Odedra; Rai-Shung Liu

Book ID
104253329
Publisher
Elsevier Science
Year
2003
Tongue
French
Weight
487 KB
Volume
44
Category
Article
ISSN
0040-4039

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✦ Synopsis

We report new ruthenium-catalyzed cis-trans isomerization of various functionalized epoxides. Enantiospecific isomerization of chiral epoxides is achieved without loss of enantiopurity, and epimerization occurs only at the epoxide carbon of the activating group.

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