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Catalytic Hydrohydrazination of a Wide Range of Alkenes with a Simple Mn Complex.

✍ Scribed by Jerome Waser; Erick M. Carreira

Book ID
101965723
Publisher
John Wiley and Sons
Year
2004
Weight
34 KB
Volume
35
Category
Article
ISSN
0931-7597

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πŸ“œ SIMILAR VOLUMES

Catalytic Hydrohydrazination of a Wide R
Catalytic Hydrohydrazination of a Wide Range of Alkenes with a Simple Mn Complex
✍ JΓ©rΓ΄me Waser; Erick M. Carreira πŸ“‚ Article πŸ“… 2004 πŸ› John Wiley and Sons 🌐 English βš– 143 KB

Heterofunctionalization reactions of olefins are highly desirable processes as they convert readily available starting materials into value-added building blocks for chemical synthesis. [1][2][3][4] In this respect, the best illustration is the role played by epoxides and diols in chemical synthesis

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Catalytic epoxidation of two unfunctionalized alkenes, 1,2\_dihydronaphthalene and tranx-e-methylstyrene, is reported using achiral and chirol (Salen)Mn(III) complexes l-3 together with a nitrogen heterocycle as axial ligand in the presence of 30 %I aqueous hydrogen peroxide as oxidant. Typically, t