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Catalytic Hydrohydrazination of a Wide Range of Alkenes with a Simple Mn Complex

✍ Scribed by Jérôme Waser; Erick M. Carreira

Book ID
101534887
Publisher
John Wiley and Sons
Year
2004
Tongue
English
Weight
143 KB
Volume
116
Category
Article
ISSN
0044-8249

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✦ Synopsis

Heterofunctionalization reactions of olefins are highly desirable processes as they convert readily available starting materials into value-added building blocks for chemical synthesis. [1][2][3][4] In this respect, the best illustration is the role played by epoxides and diols in chemical synthesis which arises from the availability of a plethora of epoxidation reagents and catalysts [2,5,6] and advances in olefin dihydroxylation. [7] However, despite the numerous processes for the

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✍ Pekka Pietikäinen 📂 Article 📅 1994 🏛 Elsevier Science 🌐 French ⚖ 311 KB

Catalytic epoxidation of two unfunctionalized alkenes, 1,2\_dihydronaphthalene and tranx-e-methylstyrene, is reported using achiral and chirol (Salen)Mn(III) complexes l-3 together with a nitrogen heterocycle as axial ligand in the presence of 30 %I aqueous hydrogen peroxide as oxidant. Typically, t