Catalytic formation of conjugated dienones from ynones by a ruthenium complex
✍ Scribed by Y. Inoue; S. Dmaizumi
- Publisher
- Elsevier Science
- Year
- 1988
- Weight
- 171 KB
- Volume
- 49
- Category
- Article
- ISSN
- 0304-5102
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📜 SIMILAR VOLUMES
The first catalytic oxidation of trifluoromethyl carbinols has been accomplished by a novel ruthenium(II) complex using sodium periodate as an oxidant. Trifluoromethyl ketones were obtained under mild conditions and in excellent yields.
Consecutive addition of one-equivalent portions of glycine ethyl ester to [(p-cymene)Ru(GGGOMeϪH + )Cl] leads to considerable amounts of (tetra-to nonapeptide)ruthenium complexes in a one-pot reaction, in which the (p-cymene)RuCl fragment acts as a catalyst. The analogous reaction with ala-
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