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Catalytic Enantioselective Addition of Organometallic Reagents to N -Formylimines Using Monodentate Phosphoramidite Ligands

✍ Scribed by Pizzuti, Maria Gabriella; Minnaard, Adriaan J.; Feringa, Ben L.


Book ID
120604723
Publisher
American Chemical Society
Year
2008
Tongue
English
Weight
145 KB
Volume
73
Category
Article
ISSN
0022-3263

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AbstractÐA variety of new chiral phosphoramidites was synthesised and tested in the copper-catalysed enantioselective conjugate addition of diethylzinc to cyclohexenone and chalcone in order to assess the structural features that are important for stereocontrol. A sterically demanding amine moiety i