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Catalytic Enantioselective Addition of Allylic Organometallic Reagents to Aldehydes and Ketones

✍ Scribed by Denmark, Scott E.; Fu, Jiping

Book ID
115527375
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
916 KB
Volume
103
Category
Article
ISSN
0009-2665

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✍ E.J Corey; Francis J Hannon πŸ“‚ Article πŸ“… 1987 πŸ› Elsevier Science 🌐 French βš– 284 KB

A mechanistic model for the enantioselective addition of diethylzinc to benzaldehyde with chiral tridentate lithium complexes as catalysts correctly predicts the observed direction of enantioselectivity which occurs at levels of 8595% ee. A recent paper from these laboratories described two rationa