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Catalytic, Enantioselective Addition of Allylsilanes to Aldehydes: Generation of a Novel, Reactive TiIV Complex from TiF4

✍ Scribed by Dr. Donald R. Gauthier Jr.; Prof. Erick M. Carreira


Publisher
John Wiley and Sons
Year
1996
Tongue
English
Weight
422 KB
Volume
35
Category
Article
ISSN
0044-8249

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πŸ“œ SIMILAR VOLUMES


Catalytic and Stoichiometric Enantiosele
✍ Dipl.-Chem. Beat Schmidt; Prof. Dr. Dieter Seebach πŸ“‚ Article πŸ“… 1991 πŸ› John Wiley and Sons 🌐 English βš– 364 KB πŸ‘ 2 views

main product 19, ca. 20% of another stereoisomer. This results from a partial racemization of the ketone 5 occurring during its distillation or during the formation of 18. This follows from the condensation of racemic 5 with the aldehyde 15 affording with a 4: 1 selectivity the above mentioned by-pr