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Catalytic effects in the claisen amino rearrangement

✍ Scribed by I. B. Abdrakhmanov; Z. N. Saraeva; N. G. Nigmatullin; G. A. Tolstikov

Book ID: 112452517
Publisher: Springer
Year: 1989
Tongue: English
Weight: 201 KB
Volume: 38
Category: Article
ISSN: 1573-9171
DOI: 10.1007/bf00978459

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## Abstract The __Claisen__ rearrangement of the __N__‐protected, silylated allyl glycinates **11** and **12** led to the formation of allyl/silyl‐functionalized amino acids **13** and **14** in yields up to 80%. The diastereoisomer ratio varied from 2 : 1 to 29 : 1 for **11mb**, and from 2 : 1 to