Allylsilane-Modified Amino Acids from th
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Mustafa Mohamed; Michael A. Brook
📂
Article
📅
2002
🏛
John Wiley and Sons
🌐
German
⚖ 180 KB
## Abstract The __Claisen__ rearrangement of the __N__‐protected, silylated allyl glycinates **11** and **12** led to the formation of allyl/silyl‐functionalized amino acids **13** and **14** in yields up to 80%. The diastereoisomer ratio varied from 2 : 1 to 29 : 1 for **11mb**, and from 2 : 1 to