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Allylsilane-Modified Amino Acids from the Claisen Rearrangement.

✍ Scribed by Mustafa Mohamed; Michael A. Brook


Publisher
John Wiley and Sons
Year
2003
Weight
207 KB
Volume
34
Category
Article
ISSN
0931-7597

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Allylsilane-Modified Amino Acids from th
✍ Mustafa Mohamed; Michael A. Brook 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 German ⚖ 180 KB

## Abstract The __Claisen__ rearrangement of the __N__‐protected, silylated allyl glycinates **11** and **12** led to the formation of allyl/silyl‐functionalized amino acids **13** and **14** in yields up to 80%. The diastereoisomer ratio varied from 2 : 1 to 29 : 1 for **11mb**, and from 2 : 1 to