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Catalytic Effect of Sulfoxides on the Fluxional Motion of 2,9-Dimethyl-1,10-phenanthroline in a Platinum(II) Complex: Evaluation of Steric and Electronic Contributions

✍ Scribed by Romeo, Raffaello; Fenech, Lucia; Carnabuci, Salvatore; Plutino, Maria Rosaria; Romeo, Andrea


Book ID
126149975
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
120 KB
Volume
41
Category
Article
ISSN
0020-1669

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Effects of counterion on the triplet sta
✍ Mikio Yagi; Takashi Kaneshima; Masafumi Torii; Keisuke Matsuo; Jiro Higuchi πŸ“‚ Article πŸ“… 1992 πŸ› Elsevier Science 🌐 English βš– 340 KB

The anisotropy of the triplet sublevel populating rates was determined for 1 , 1 0-phenanthroline ( phen), 2,9dimethyl-1,l Ophenanthroline (2,9-Me2phen) and their zinc(H) complexes in rigid solutions and for ZnClz(2,9-Merphen) in the crystalline state at 77 K by a time-resolved EPR technique. The su