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Effects of Sterics and Electronic Delocalization on the Photophysical, Structural, and Electrochemical Properties of 2,9-Disubstituted 1,10-Phenanthroline Copper(I) Complexes

✍ Scribed by Miller, Mark T.; Gantzel, Peter K.; Karpishin, Timothy B.


Book ID
127143882
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
120 KB
Volume
38
Category
Article
ISSN
0020-1669

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## Abstract A series of copper(II) and copper(I) complexes, [CuX~2~L] (1–6) and [CuL~2~](CuX~2~) (7–12) (X = Cl, Br; L = 2‐R‐9‐R′‐1,10‐phenanthroline, dpp: R = Rβ€² = Ph; npp: R = naphthyl, Rβ€² = Ph; dnp: R = Rβ€² = naphthyl) were synthesized and characterized by elemental analysis, UV/Vis and IR spectr