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Catalytic Dehalogenation of Aryl Chlorides Mediated by Ruthenium(II) Phosphine Complexes

✍ Scribed by Cucullu, Michèle E.; Nolan, Steven P.; Belderrain, Tomás R.; Grubbs, Robert H.


Book ID
127337978
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
193 KB
Volume
18
Category
Article
ISSN
0276-7333

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Catalytic asymmetric hydrogenation of cy
✍ Kohtaro Osakada; Masamichi Obana; Takao Ikariya; Masahiko Saburi; Sadao Yoshikaw 📂 Article 📅 1981 🏛 Elsevier Science 🌐 French ⚖ 237 KB

Optically active y-and d-lactones are obtained by the hydrogenation of five-and six-membered cyclic anhydrides using a Ru(I1) complex with chiral phosphine ligand, DIOP, as a catalyst. Catalytic asymmetric hydrogenation with transition metal complexes has stereoselective addition of a hydrogen molec