Kohlenforschung at Mülheim an der Ruhr for their kind support and their help in performing the reactions in supercritical carbon dioxide. Preparation for the synthesis of polyketones in scCO 2 : Compound 4 e (5.5 mg, 0.006 mmol) was transferred to a 20-mL autoclave under N 2 . The solution was pres
✦ LIBER ✦
Catalytic Copolymerization of Ethene and Carbon Monoxide on Nickel Complexes
✍ Scribed by Bernd Domhöver; Wolfgang Kläui; Andreas Kremer-Aach; Ralf Bell; Dietrich Mootz
- Publisher
- John Wiley and Sons
- Year
- 1998
- Tongue
- English
- Weight
- 96 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
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## Abstract Monocoordinate nickel/__N__‐heterocyclic carbene complexes reveal unexpected reactivity towards aryl fluorides. Defluorination reactions were efficiently performed with a β‐hydrogen‐containing alkoxide (3 equiv.) in the presence of 3 mol % of [1:1] Ni(0)/IMes⋅HCl catalyst (IMes=1,3‐dime