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Catalytic C−H Activation of Hydrocarbons by Rhodium(I) and Iridium(I) Complexes with Hemilabile Quinolyl-Cp Ligands †

✍ Scribed by Kohl, Gerald; Rudolph, Ralph; Pritzkow, Hans; Enders, Markus

Book ID
120648512
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
161 KB
Volume
24
Category
Article
ISSN
0276-7333

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📜 SIMILAR VOLUMES

Rhodium(III) and Iridium(III) Complexes
Rhodium(III) and Iridium(III) Complexes with Quinolyl-Functionalized Cp Ligands: Synthesis and Catalytic Hydrogenation Activity
✍ Gerald Kohl; Hans Pritzkow; Markus Enders 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 203 KB

## Abstract Bis(ethene) complexes of rhodium(I) and iridium(I) with 8‐quinolylcyclopentadienyl ligands (Cp^Q^ and Cp^Q^\*) were oxidized by a photochemically induced reaction with chlorine‐containing solvents or by treatment with iodine. Upon this oxidation, the quinoline ring rotates and the N don