Catalytic activity of some cationic complexes of rhodium(I) and iridium(I) with 1,10-phenanthroline and similar ligands
✍ Scribed by G. Zassinovich; G. Mestroni; A. Camus
- Publisher
- Elsevier Science
- Year
- 1977
- Weight
- 190 KB
- Volume
- 2
- Category
- Article
- ISSN
- 0304-5102
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Some new Rh(1) and Ir(1) complexes of the types [(COD)M(LL)]ClO, and [(COD)MCI], [COD = cyclooctadiene; M = Rh, Ir; LL = 1,l'-bis(dipheny1phosphino)ferrocene (DPPF), 1 -diphenylphosphino-2-(N,N-dimethylamino)methylferrocene (FcNP), 1,6-diferrocenyl-2,5diazahexane (FcNN)] were prepared, and their cat
## Abstract The mononuclear cationic Rh^I^ complexes [Rh(cod)(mdd)]^+^X^−^ and [Rh(CO)~2~(mdd)]^+^X^−^ (X = BPh~4~, PF~6~) containing the chelating bidentate __N__‐heterocyclic carbene ligand 1,1′‐methylene‐3,3′‐dimethyldiimidazoline‐2,2′‐diylidene (mdd) have been synthesised and spectroscopically