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Catalytic Asymmetric Synthesis of Epoxides from Aldehydes Using Sulfur Ylides with In Situ Generation of Diazocompounds

✍ Scribed by Varinder K. Aggarwal; Emma Alonso; George Hynd; Kevin M. Lydon; Matthew J. Palmer; Marina Porcelloni; John R. Studley


Publisher
John Wiley and Sons
Year
2001
Tongue
English
Weight
92 KB
Volume
40
Category
Article
ISSN
0044-8249

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✍ Ryuuichirou Hayakawa; Makoto Shimizu πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 33 KB

Synthesis of Chiral Epoxides from Aldehydes Using Sulfur Ylide Derived from Reduced Product of Baker's Yeast Reduction. -Baker's yeast reduction of the cyclic Ξ²-keto esters (I) provides an enantiomerically pure Ξ²-hydroxy ester (II) in the presence of sulfur compounds as additives. A sulfur ylide der