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Catalytic asymmetric synthesis of descurainin via 1,3-dipolar cycloaddition of a carbonyl ylide using Rh2(R-TCPTTL)4

โœ Scribed by Naoyuki Shimada; Taiki Hanari; Yasunobu Kurosaki; Masahiro Anada; Hisanori Nambu; Shunichi Hashimoto


Book ID
104098446
Publisher
Elsevier Science
Year
2010
Tongue
French
Weight
474 KB
Volume
51
Category
Article
ISSN
0040-4039

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Diastereoselective synthesis of pyrrolid
โœ K. Karthikeyan; R. Senthil Kumar; D. Muralidharan; P.T. Perumal ๐Ÿ“‚ Article ๐Ÿ“… 2009 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 691 KB

1,3-Dipolar cycloaddition of D-glucose-derived azomethine ylides for the synthesis of chiral pyrrolidines accompanied an unexpected 1,2-elimination in the furanose moiety of the products. The C3 0 alkoxy/ hydroxy group of the furanose moiety was invariably eliminated under the reaction conditions. A