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Catalytic Asymmetric Cyanosilylation of Ketones by a Chiral Amino Acid Salt

โœ Scribed by Liu, Xiaohua; Qin, Bo; Zhou, Xin; He, Bin; Feng, Xiaoming

Book ID
127158368
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
39 KB
Volume
127
Category
Article
ISSN
0002-7863

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The asymmetric cotalytic cyanosilylationof oliphaticaldehydes with Me3SiCN using (R)-BINOL-Ti(O-i-Pr)2 m an arymmem"c precakdyst is shown to proceed smoothly in dichloromethane to ~ford the cyanohydrinsin rekdvely high enantiose!ectivity (up @ 75~oee). @1997 Elsevier ScienceLtd. Recently,much inter