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Catalytic Asymmetric Construction of Quaternary α-Amino Acid Containing Pyrrolidines through 1,3-Dipolar Cycloaddition of Azomethine Ylides to α-Aminoacrylates

✍ Scribed by Wang, Zheng; Luo, Shuai; Zhang, Shoude; Yang, Wu-Lin; Liu, Yang-Zi; Li, Honglin; Luo, Xiaoyan; Deng, Wei-Ping


Book ID
120159688
Publisher
John Wiley and Sons
Year
2013
Tongue
English
Weight
601 KB
Volume
19
Category
Article
ISSN
0947-6539

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## Abstract The first catalytic asymmetric 1,3‐dipolar cycloaddition of azomethine ylides with various sterically hindered α,α,β‐trisubstituted 2‐alkylidene‐cycloketones has been developed successfully with silver acetate/TF‐BiphamPhos complex for the construction of spiro heterocyclic compounds co