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Catalytic asymmetric allylation of aldehydes with BINOL-Ti(IV) complex accelerated by i-PrSSiMe3

✍ Scribed by Chan-Mo Yu; Ha-Soon Choi; Won-Hyuk Jung; Sung-Soo Lee

Book ID: 103404462
Publisher: Elsevier Science
Year: 1996
Tongue: French
Weight: 203 KB
Volume: 37
Category: Article
ISSN: 0040-4039
DOI: 10.1016/0040-4039(96)01582-1

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ChemInform Abstract: Catalytic Asymmetric Allylation of Aldehydes with BINOL-Ti(IV) Complex Accelerated by i-PrSSiMe3.

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Catalytic allylic transfer reactions of functionalized aldehydes promoted by BINOL-Ti(IV) with synergistic reagent

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Practical and efficient catalytic asymmetric allylic transfer reactions of tin reagents promoted by BINOL-Ti[OCH(CF 3 ) 2 ] 2 complex by the utilization of t-BuSBEt 2 are successful with a variety of functionalized aldehydes containing ketone, aldehyde, ester, amide, or carbamoyl functionality and a

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## Abstract For Abstract see ChemInform Abstract in Full Text.

ChemInform Abstract: Effects of Subjoin

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A new, chiral bidentate Ti(IV) complex of type 1 was successfully designed and can be utilized for simultaneous coordination to aldehyde carbonyls, thereby allowing the precise enantioface discrimination of such carbonyls for a new catalytic, practical enantioselective allylation of aldehydes with a

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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v