𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Catalytic Asymmetric Allylation of Aldehydes Using a Chiral Silver(I) Complex

✍ Scribed by Yanagisawa, Akira; Nakashima, Hiroshi; Ishiba, Atsushi; Yamamoto, Hisashi


Book ID
120712037
Publisher
American Chemical Society
Year
1996
Tongue
English
Weight
102 KB
Volume
118
Category
Article
ISSN
0002-7863

No coin nor oath required. For personal study only.


πŸ“œ SIMILAR VOLUMES


Catalytic Asymmetric Allylation of Aldeh
✍ Piotr Kwiatkowski; Wojciech Chaladaj; Janusz Jurczak πŸ“‚ Article πŸ“… 2006 πŸ› John Wiley and Sons βš– 34 KB πŸ‘ 2 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.

Asymmetric Catalytic Cyanosilylation of
✍ Maki Mori; Hironori Imma; Takeshi Nakai πŸ“‚ Article πŸ“… 1997 πŸ› Elsevier Science 🌐 French βš– 478 KB

The asymmetric cotalytic cyanosilylationof oliphaticaldehydes with Me3SiCN using (R)-BINOL-Ti(O-i-Pr)2 m an arymmem"c precakdyst is shown to proceed smoothly in dichloromethane to ~ford the cyanohydrinsin rekdvely high enantiose!ectivity (up @ 75~oee). @1997 Elsevier ScienceLtd. Recently,much inter

Catalytic asymmetric allylations of achi
✍ Michio Kurosu; Miguel Lorca πŸ“‚ Article πŸ“… 2002 πŸ› Elsevier Science 🌐 French βš– 137 KB

The complex generated from BINOL, Zr(O t Bu) 4 , and 4 A , MS in toluene-pivalonitrile is very effective for catalytic asymmetric allylation of aldehydes using allyltributyltin. The reactions of achiral aldehyde under these conditions are completed within 3 h using 10-20 mol% of the complex at -20Β°C

Practical approach for catalytic asymmet
✍ Satoshi Kii; Keiji Maruoka πŸ“‚ Article πŸ“… 2001 πŸ› Elsevier Science 🌐 French βš– 111 KB

A new, chiral bidentate Ti(IV) complex of type 1 was successfully designed and can be utilized for simultaneous coordination to aldehyde carbonyls, thereby allowing the precise enantioface discrimination of such carbonyls for a new catalytic, practical enantioselective allylation of aldehydes with a