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Catalytic Asymmetric Addition of Dimethylzinc to α-Ketoesters, Using Mandelamides as Ligands.

✍ Scribed by Gonzalo Blay; Isabel Fernandez; Alicia Marco-Aleixandre; Jose R. Pedro

Publisher
John Wiley and Sons
Year
2006
Weight
20 KB
Volume
37
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

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✍ Yoshitaka Hamashima; Naoki Sasamoto; Daido Hotta; Hidenori Somei; Natsuko Umebay 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 128 KB 👁 1 views

Addition reactions of metal enolates of carbonyl compounds to imines, the so-called Mannich-type reaction, represent an important class of carbon-carbon bond-forming reactions. [1] Reflecting the potential utility of the Mannich adducts in the synthesis of nitrogen-containing compounds, [2] we [3] a