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Catalytic Asymmetric Addition of β-Ketoesters to Various Imines by Using Chiral Palladium Complexes.

✍ Scribed by Yoshitaka Hamashima; Naoki Sasamoto; Daido Hotta; Hidenori Somei; Natsuko Umebayashi; Mikiko Sodeoka

Publisher
John Wiley and Sons
Year
2005
Weight
49 KB
Volume
36
Category
Article
ISSN
0931-7597

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Addition reactions of metal enolates of carbonyl compounds to imines, the so-called Mannich-type reaction, represent an important class of carbon-carbon bond-forming reactions. [1] Reflecting the potential utility of the Mannich adducts in the synthesis of nitrogen-containing compounds, [2] we [3] a

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