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Catalytic Amination of Long Chain Aliphatic Alcohols

✍ Scribed by Baiker, Alfons; Richarz, Werner


Book ID
120530021
Publisher
American Chemical Society
Year
1977
Weight
646 KB
Volume
16
Category
Article
ISSN
0196-4321

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Synthesis of long chain aliphatic amines
✍ A. Baiker; W. Richarz 📂 Article 📅 1977 🏛 Elsevier Science 🌐 French ⚖ 87 KB

The synthesis of long chain aliphatic amines is of particular interest since they are widely used as corrosion inhibitors, epoxy hardeners, textile additives etc. (1,2). Several ways of synthesis are known, starting from olefines (1,3), fatty acids (1,4) or from the corresponding alcohols (1,5,6).

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## Abstract A catalytic one step procedure for the C(1), C(2)‐bond cleavage of long‐chain aliphatic alcohols and ω‐phenyl alcohols has been investigated, using as examples decanol, dodecanol, hexadecanol, benzyl alcohol, 2‐phenylethanol and 3‐phenyl‐propanol. The reactions, which were carried out i

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✍ Macgregor, J. H. ;Ward, F. 📂 Article 📅 1947 🏛 Wiley (John Wiley & Sons) ⚖ 272 KB

## Abstract A method of acylating long chain primary aliphatic amines is described. Representative series of N‐monoalkylstearamides, N,N′‐dialkyladipamides and N,N′‐dialkylsebacamides, in which each alkyl radical contains between 8 and 18 carbon atoms, have been prepared by acylating the long chain