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Catalytic C(1), C(2)-Bond Cleavage of Long-Chain Aliphatic Alcohols and ω-Phenylalkyl Alcohols

✍ Scribed by Alfons Baiker; Werner Richarz

Publisher: John Wiley and Sons
Year: 1977
Tongue: German
Weight: 271 KB
Volume: 60
Category: Article
ISSN: 0018-019X
DOI: 10.1002/hlca.19770600848

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✦ Synopsis

Abstract

A catalytic one step procedure for the C(1), C(2)‐bond cleavage of long‐chain aliphatic alcohols and ω‐phenyl alcohols has been investigated, using as examples decanol, dodecanol, hexadecanol, benzyl alcohol, 2‐phenylethanol and 3‐phenyl‐propanol. The reactions, which were carried out in a continuous flow tubular reactor using a Ni/Cu catalyst, showed good activity and selectivity with respect to the cleavage products. On the basis of the experimental studies a reaction scheme for the heterogeneous catalytic C(1), C(2)‐bond cleavage of the alcohols is suggested.

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