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Catalysis of olefin hydrogenation and allylic isomerization by immobilized gold nanoclusters

✍ Scribed by V. V. Smirnov; S. A. Nikolaev; L. A. Tyurina; A. Yu. Vasil’kov


Book ID
110196574
Publisher
Springer
Year
2006
Tongue
English
Weight
164 KB
Volume
46
Category
Article
ISSN
0965-5441

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Ruthenium-carbenoid catalysts such as Grubbs' complex I mediate efficiently the isomerization of b,g-unsaturated ethers and amines to the corresponding vinyl ethers and enamines. This reaction can be useful in the deprotection of allyl and homoallyl ethers as well as amines.