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Olefin isomerization by a ruthenium carbenoid complex. Cleavage of allyl and homoallyl groups

✍ Scribed by Christine Cadot; Peter I Dalko; Janine Cossy

Publisher: Elsevier Science
Year: 2002
Tongue: French
Weight: 99 KB
Volume: 43
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(02)00141-7

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✦ Synopsis

Ruthenium-carbenoid catalysts such as Grubbs' complex I mediate efficiently the isomerization of b,g-unsaturated ethers and amines to the corresponding vinyl ethers and enamines. This reaction can be useful in the deprotection of allyl and homoallyl ethers as well as amines.

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