Catalysis of hydrogen production in irradiated aqueous solutions by gold sols
β Scribed by Meisel, D.
- Book ID
- 127274702
- Publisher
- American Chemical Society
- Year
- 1979
- Tongue
- English
- Weight
- 409 KB
- Volume
- 101
- Category
- Article
- ISSN
- 0002-7863
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π SIMILAR VOLUMES
The decay oi H-atoms in several y-irradiated aqueous solutions was examined by ESR spectroscopy from 'UΒ°K to 150Β°K. In perchloric acid the decay indicates the presence of two trapping sites. The more strongly trapped H-atoms decay by a first-order process, apparently resulting from a slow release fr
**Shortβlived radicals such as __(1)__ can be compelled to undergo unusual reactions** if they are generated in the presence of a metal colloid catalyst in aqueous solution. Instead of combining, disprotionating, or dismuting, the radicals __(1)__ participate in a redox process leading to evolution