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Catalysis of ester aminolysis by macrocyclic ionophores

✍ Scribed by Gandour, Richard D.; Walker, David A.; Nayak, Ashutosh; Newkome, George R.

Book ID
118231068
Publisher
American Chemical Society
Year
1978
Tongue
English
Weight
258 KB
Volume
100
Category
Article
ISSN
0002-7863

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## Abstract Various pathways for the reaction of methylamine with methyl acetate catalyzed by 2(1__H__)‐pyridone have been investigated at the Becke3LYP/6–31G^\*\*^/HF/6–31G^\*\*^ level of theory. The most favorable pathway consists of a one‐step reaction, in which all bond‐forming and ‐breaking pr