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Catalysis of enantiomeric ester hydrolysis by N-decanoyl-L-histidine in polymer domains

✍ Scribed by Ihara, Yasuji ;Kimura, Yoshiharu ;Nango, Mamoru ;Kuroki, Nobuhiko

Publisher: John Wiley and Sons
Year: 1983
Weight: 343 KB
Volume: 21
Category: Article
ISSN: 0360-6376
DOI: 10.1002/pol.1983.170210525

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✦ Synopsis

Abstract

Catalytic hydrolysis of enantiomeric substrates by N‐decanoyl‐L‐histidine was studied at pH 7.30, 0.02__M__ phosphate buffer, and 25°C in the presence of quaternized polymers. The rate of reaction is remarkably accelerated in the presence of polyethylenimine derivatives, but the observed stereoselectivity depends on the structure of the substrates.

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