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Catalysis by Amino Acid-Derived Tetracoordinate Complexes: Enantioselective Addition of Dialkylzincs to Aliphatic and Aromatic Aldehydes

✍ Scribed by Dangel, Brian D.; Polt, Robin

Book ID: 126101755
Publisher: American Chemical Society
Year: 2000
Tongue: English
Weight: 79 KB
Volume: 2
Category: Article
ISSN: 1523-7060
DOI: 10.1021/ol0063151

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## Abstract Enantioselective addition of diethylzinc to a series of aromatic aldehydes was developed using a modular amino acid amide chiral ligand (2__S__)‐3‐phenyl‐__N__‐((__R__)‐1‐phenyl‐ethyl)‐2‐(tosylamino)propanamide without using titanium complex. The catalytic system employing 10 mol% of 1g