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Cascade Reactions of Captodative Formyl(amino)alkenes with N,O-Binucleophiles.

✍ Scribed by Alexander Yu. Rulev; Lyudmila I. Larina; Yuri A. Chuvashev; Vladimir V. Novokshonov

Publisher: John Wiley and Sons
Year: 2005
Weight: 19 KB
Volume: 36
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200538136

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✦ Synopsis

Abstract

For Abstract see ChemInform Abstract in Full Text.

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## Abstract Novel tricyclic 4‐(trifluoromethyl)‐[1,2,3]triazolo[1,5‐__a__]quinoxalines were readily prepared from __N__‐(__o__‐haloaryl)alkynylimines and sodium azide __via__ copper(I)‐catalyzed tandem reactions. This synthetic strategy provides an efficient way to access a library of novel heteroc