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Copper(I)-Catalyzed Synthesis of Novel 4-(Trifluoromethyl)-[1,2,3]triazolo[1,5-a]quinoxalines via Cascade Reactions of N-(o-Haloaryl)alkynylimine with Sodium Azide

✍ Scribed by Zixian Chen; Jiangtao Zhu; Haibo Xie; Shan Li; Yongming Wu; Yuefa Gong


Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
203 KB
Volume
352
Category
Article
ISSN
1615-4150

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✦ Synopsis


Abstract

Novel tricyclic 4‐(trifluoromethyl)‐[1,2,3]triazolo[1,5‐a]quinoxalines were readily prepared from N‐(o‐haloaryl)alkynylimines and sodium azide via copper(I)‐catalyzed tandem reactions. This synthetic strategy provides an efficient way to access a library of novel heterocyclic compounds that are of interest in drug discovery.