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Carboxylation reactions involving carbon dioxide insertion into palladium–carbon σ-bonds

✍ Scribed by Johnson, Magnus T.; Wendt, Ola F.


Book ID
121467588
Publisher
Elsevier Science
Year
2014
Tongue
English
Weight
741 KB
Volume
751
Category
Article
ISSN
0022-328X

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First Insertion Reaction of Carbon Monox
✍ Prof. Dr. Ekkehard Lindner; Dipl.-Chem. Günter von Au 📂 Article 📅 1980 🏛 John Wiley and Sons 🌐 English ⚖ 229 KB

A solution of ( I l i ) (10 g, 19.3 mmol) in 80 ml of anhydrous toluene, which contains 5 ml ethanol, is heated under reflux for 12 h. The solvent is removed and the residue digested with 50 ml pentane. Precipitated Ph3P0 is separated off and the previously unknown 4,5,6,6a-tetrahydro-2( 1 H)-pental