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Carbonyl Ylide Cycloadditions to C,C-Double Bonds of Methylenecyclopropanes

✍ Scribed by Alexander P. Molchanov; Vyacheslav V. Diev; Jörg Magull; Denis Vidović; Sergei I. Kozhushkov; Armin de Meijere; Rafael R. Kostikov

Publisher
John Wiley and Sons
Year
2005
Tongue
English
Weight
156 KB
Volume
2005
Category
Article
ISSN
1434-193X

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✍ Gerardo M. Ramos Tombo; Camille Ganter 📂 Article 📅 1982 🏛 John Wiley and Sons 🌐 German ⚖ 412 KB

## Abstract The tricyclic olefinic primary amine **1** readily cyclizes to the tetracyclic secondary amine **2** at approximately 200° in protic as well as aprotic solvents although the C, C‐double bond is not activated by electron‐attracting groups. This unusual intramolecular addition is the cons