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1,3-Dipolar Cycloaddition of Fluorinated Azomethine Ylides at the C=N Bond.

✍ Scribed by M. S. Novikov; A. F. Khlebnikov; M. A. Egarmin; J. Kopf; R. R. Kostikov

Publisher
John Wiley and Sons
Year
2005
Weight
16 KB
Volume
36
Category
Article
ISSN
0931-7597

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## Abstract Azomethine ylides generated from 5‐(alkoxycarbonylmethyl)phenanthridinium cations were studied in 1,3‐dipolar cycloadditions with dimethyl maleate and dimethyl fumarate as dipolarophiles. The cycloadducts with the pyrrolidino[1,2‐f]phenanthridine skeleton easily underwent dehydrogenatio