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Carbonyl-Monoolefin-Derivate des Chroms, Molybdäns und Wolframs, III. Darstellung und Reaktivität von Tricarbonyl-Chelatphosphan-Olefin-Komplexen

✍ Scribed by Schenk, Wolfdieter A. ;Müller, Helmut


Publisher
Wiley (John Wiley & Sons)
Year
1982
Tongue
English
Weight
717 KB
Volume
115
Category
Article
ISSN
0009-2940

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✍ Weber, Lothar ;Matzke, Thomas ;Boese, Roland 📂 Article 📅 1990 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 712 KB

The phosphavinylidene complexes (q5-C5HS)(CO),M= P = C(Si-(CO),M -CH2-P[CH(SiMe,),][CH = S(O)Me,] (6a, b) by ex-(3, M = Mo (a); W (b)] react with equimolar amounts of cess of ylide. Constitution and configuration of 5 and 6 were sulfur ylide Me,S(0)=CH2 (1) to afford the red metallophos-established