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Carbonyl compounds as primary products in the reduction of alkyldioxycobaloximes by sodium borohydride

โœ Scribed by Bied-Charreton, Claude; Gaudemer, Alain

Book ID
126994526
Publisher
American Chemical Society
Year
1976
Tongue
English
Weight
241 KB
Volume
98
Category
Article
ISSN
0002-7863

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The reduction of ketones and some esters by sodium borohydride is dramatically accelerated by uv irradiation. The reaction seems to proceed from the (n, .rr\*) excited state of the carbonyl compound. The photocatalytic effect is dependent on the solvent polarity and substituents on aromatic carboxyl