As part of a study of the reactions of sulfines with carbenoid reagents, we have initiated a study of the reactions of aromatic sulfines with diazo compounds. While this study was in progress, Strating and his coworkers reported that 9-diazofluorene reacts with dichlorosulfine to form 9-dichloro-2 m
CarbonversusSulfur Addition of Nucleophiles to Sulfines. Part I. The Case of Sulfinates
โ Scribed by Ibrahim El-Sayed
- Publisher
- Springer Vienna
- Year
- 2004
- Tongue
- English
- Weight
- 193 KB
- Volume
- 136
- Category
- Article
- ISSN
- 0026-9247
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๐ SIMILAR VOLUMES
Trimethylsilylcyanide has been added to a number of aldehydes using a highly active chiral catalyst. This procedure gives the TMS ethers of the corresponding cyanohydrins in excellent chemical yields with enantiomeric excesses of up to 59%. The reaction is believed to occur through hypervalent silic
Studies have been carried out on the addition of trimethylsilylcyanide to aldehydes using highly active chiral lithium phenolate catalysts. The screening of a number of chiral phenolates has resulted in a system which gives the TMS ethers of cyanohydrins in excellent chemical yields with enantiomeri