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Carbon−Carbon Bond Formation Reaction of Zirconacyclopentadienes with Alkynes in the Presence of Ni(II)-complexes

✍ Scribed by Takahashi, Tamotsu; Tsai, Fu-Yu; Li, Yanzhong; Nakajima, Kiyohiko; Kotora, Martin

Book ID
127029790
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
201 KB
Volume
121
Category
Article
ISSN
0002-7863

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ChemInform Abstract: Carbon—Carbon Bond
ChemInform Abstract: Carbon—Carbon Bond Formation Reaction of Zirconacyclopentadienes with Alkynes in the Presence of Ni(II)-Complexes.
✍ Tamotsu Takahashi; Fu-Yu Tsai; Yanzhong Li; Kiyohiko Nakajima; Martin Kotora 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 47 KB 👁 2 views

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Selective one carbon-carbon bond formati
Selective one carbon-carbon bond formation reaction of zirconacyclopentadienes with aryl iodides or alkynyl iodides
✍ Tamotsu Takahashi; Wen-Hua Sun; Chanjuan Xi; Ubayama Haruka; Zhenfeng Xi 📂 Article 📅 1998 🏛 Elsevier Science 🌐 French ⚖ 599 KB

Reaction of zirconacyclopentadienes with one equiv or two equiv of aryl iodides in the presence of CuCI and DMPU afforded mono-arylated diene derivatives in high yields with high selectivities. Treatment of zirconacyclopentadienes with one equiv of 2-thienyl iodide similarly gave thienyldienes in th