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Carbon−Carbon Bond Formation on a Bis(oxazolinyl)phenyl−Rhodium Complex in a Reduction and Oxidative Addition Sequence

✍ Scribed by Ito, Jun-ichi; Miyakawa, Takeshi; Nishiyama, Hisao


Book ID
125897535
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
155 KB
Volume
25
Category
Article
ISSN
0276-7333

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✍ Jun-ichi Ito; Hisao Nishiyama 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 144 KB 👁 1 views

## Abstract Thermolysis of the rhodium(III) complex [(__dm__‐Phebox‐__dm__)Rh(OAc)~2~(H~2~O)] [1; __dm__‐Phebox‐__dm__ = 2,6‐bis(4,4‐dimethyloxazolinyl)phenyl] in various arenes results in the formation of the corresponding aryl complexes [(__dm__‐Phebox‐__dm__)Rh(Ar)(κ^2^‐OAc)] [Ar = C~6~H~5~ (2),